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A Kinetic Study of Silver Electrodeposition Onto Pt Ultramicroelectrodes From Amoniacal Solutions



Alvarez Romero, Giaan Arturo

2020

Corona-Castro, Jair A; Álvarez-Romero, Giaan A; Rivera, Margarita; Sausedo-Solorio, José M; Rios-Reyes, Clara H; Mendoza-Huizar, Luis H; A Kinetic Study of Silver Electrodeposition Onto Pt Ultramicroelectrodes From Amoniacal Solutions. Croatica Chemica Acta, 2020 Vol. 93 No. 3. https://doi.org/10.5562/cca3771


Abstract


A kinetic study of the Ag electrodeposition onto Pt ultramicroelectrodes of 10, 15 and 25 m of diameter from an aqueous solution containing AgNO3 1 mM + NH4NO3 0.1 M was conducted at overpotential conditions through potentiostatic studies. The analysis of the current density transients indicates the existence of two 2D nucleation and growth processes previous to the 3D nucleation and growth process.






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