Synthesis, structural characterization, and activity on the transfer hydrogenation reaction of dimesitylacetonate piano stool organometallic complexes of Ru(II), Rh(III), and Ir(III)
Alvarado Rodríguez, José Guadalupe
2019
Ibarra-Vazquez, MF., Alvarado-Rodriguez, Jose G.,Esqueda, AC., Rangel-Salas, I. I., Serrano, O., structural characterization, and activity on the transfer hydrogenation reaction of dimesitylacetonate piano stool organometallic complexes of Ru(II), Rh(III), and Ir(III). Journal of Molecular Structure, 2019, 1191, 52-58.DOI: 10.1016/j.molstruc.2019.04.029
Abstract
A new small family of Ru, Rh, and Ir piano-stool complexes partially containing the bulky acacdiMes, p-Cymene and Cp* ligands was synthetized and characterized. Their catalytic activity in transfer hydrogenation reaction was tested. The turn over frequency (TOF) values for aromatic- and alkyl-ketones giving the corresponding desired alcohols were increased in two orders of magnitude by using microwave heating compared with conventional thermal method.
Related articles
Mild Oxidation of C?C Bonds of Benzoiridacycles
Synthesis and crystal structure of the N-8-(diphenyl-hydroxy-2-aminomethylpyridine)borane
Structural Studies by NMR and X-Ray Crystallography of N-(p-Toluenesulfonyl)-Amino Acids