Synthesis and characterization of monoanionic salts of p-tertbutylcalix[7]arene
González Montiel, Simplicio
2018
Synthesis and characterization of monoanionic salts of p-tert-butylcalix[7]arene, MarianaFlores-Jarillo, Simplicio González-Montiel, Verónica Salazar-Pereda, Daniel Mendoza-Espinosa, Journal of Organometallic Chemistry 862 (2018) 53-57.
Abstract
The synthesis and full characterization of a new series of p-tert-butylcalix [7]arene (tBuC7) monoanionsof the type tBuC7M (M Na, K, Rb, Cs) is reported. Crystal structures of tBuC7K and tBuC7Rb featuremonomeric units and represent the first examples of solid state characterized tBuC7 salts. The alkalimetal base strength and reaction stoichiometry used for the selective formation of monoanionic speciesis discussed.
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