Synthesis and characterization of monoanionic salts of p-tertbutylcalix[7]arene
Mendoza Espinosa, Daniel
2018
Synthesis and characterization of monoanionic salts of p-tertbutylcalix[7]arene, Mariana Flores-Jarillo, Simplicio Gonzalez-Montiel, Verónica Salazar-Pereda, Daniel Mendoza-Espinosa, Journal of Organometallic Chemistry 862 (2018) 53-57.
Abstract
The synthesis and full characterization of a new series of p-tert-butylcalix [7]arene (tBuC7) monoanionsof the type tBuC7M (M Na, K, Rb, Cs) is reported. Crystal structures of tBuC7K and tBuC7Rb featuremonomeric units and represent the first examples of solid state characterized tBuC7 salts. The alkalimetal base strength and reaction stoichiometry used for the selective formation of monoanionic speciesis discussed.
Related articles
Trapping enols of esters and lactones with diazomethane
Synthesis of Bromoindole Alkaloids from Laurencia brongniartii
Role of lipid peroxidation in biliary obstruction in the rat.
Cleavage of alkoxycarbonyl protecting groups from carbamates by t-BuNH2
Regioselective Synthesis of 3-Indolyl(alkoxy)acetates
Synthesis of Acetamido(indole-3-yl)propanol Derivatives
Configuration, stereodynamics and crystal structure of 3-substituted-2-oxofuro[2,3-b]indoles
Total Syntheses of Five Indole Alkaloids from the Marine Bryozoan Flustra foliacea