2014
O-Ethyl S-{(S)-1-oxo-1-[(R)-2-oxo-4-phenyloxazolidin-3-yl]propan-2-yl} Carbonodithioate, J. Pablo García-Merinos, Heraclio López-Ruiz, Yliana López y Susana Rojas-Lima,Acta Crystallographica Section E, E70, o584-o585, (2014). DOI:10.1107/S1600536814007636
Abstract
In the title compound, C15H17NO4S2, synthesized by additionof O-ethylxanthic acid potassium salt to a diastereomericmixture of (4R)-3-(2-chloropropanoyl)-4-phenyloxazolidin-2-one, the oxazolidinone ring has a twist conformation on theC?C bond. The phenyl ring is inclined to the mean plane ofthe oxazolidinone ring by 76.4 (3). In the chain the methine Hatom is involved in a C?H S and a C?H O intramolecularinteraction. In the crystal, molecules are linked byC?H interactions, forming chains along [001]. The Sconfiguration at the C atom to which the xanthate group isattached was determined by comparison to the known Rconfiguration of the C atom to which the phenyl group isattached.
Furocoumarins of three species of the genus Dorstenia
Et3B, an Efficient Mediator for Xanthate Transfer Based Radical Processes
Structural studies of spiroarsoranes derived from 2-aminophenols
O-benzyl-N-(2-furoyl)thiocarbamate
Bis(acetylsalicylato-j2O,O00)diaquacadmium(II)
The Structural Chemistry of N-Monolithium Borazines
Diastereoselective alkylation of chiral glycinate derivatives containing the ?-phenylethyl group.
Diastereoselective alkylation of chiral glycinate derivatives containing the ?-phenylethyl group.