Scientific Production Faculty

Quantification of As(III) by Swasv on Glassy Carbon Electrode Codeposit Copper with Presence of B-Ciclodextrin



Mendoza Huizar, Luis Humberto

2013

López-Vargas, E., Galán-Vidal, C.A., Rodríguez-Ávila, J.A., Álvarez-Romero, G.A. Mendoza-Huizar, L.H. ECS Trans.. 2013, 47(1), 131-136.


Abstract


Nowadays, the ability to detect arsenic in drinking water is a very important subject because of arsenic's toxicity. In this sense, it is necessary to have economical and portable detection methodologies in order to control water quality, mainly in remote communities without access to expensive equipment such as atomic absorption. Currently, electrochemical methods are a low cost alternative which can be used outside the laboratory; however, these techniques use toxic or precious metals as working electrodes. The main interference in the quantification of arsenic is the Cu(II) because an intermetallic compound is formed with arsenic. In this paper we explore the co-deposition of Cu on a glassy carbon electrode to quantify As(III) in H2SO4 as a supporting electrolyte. The methodology reported a detection limit of 5.2 ?g L-1, helpful to following the official guidelines. Zn2+, Fe2+, Pb2+, Hg2+ and Cl- are not significant interferences in quantification.



Research Product




Related articles

Do Spiroarsoranes Exhibit Polytopal Equilibrium in Solution?

Analysis of the Pressure-Temperature Behavior in the Isotropic-Nematic Transition of p-Azoxianis...

Nucleation and growth of cobalt onto different substrates: Part I. Underpotential deposition onto a ...

Electrochemical kinetic study about cobalt electrodeposition onto GCE and HOPG substrates from sulfa...

A theoretical quantum study on the distribution of electrophilic and nucleophilic active sites on th...

A Semiempirical PM6 Study of Some Aminopyrimidine Derivatives and their Interaction with an Iron Sur...

Hydrogen bond studies in substituted N-(2-hydroxyphenyl)--2-[(4-methylbenzenesulfonyl)amino]acetamid...

Theoretical and Experimental Study of Cobalt Nucleation and Growth onto Gold Substrate with Differen...

Evaluation of Aromatic Steroids as Thermal Maturity Indicators in Rock Extracts

Synthesis of Zn compounds derived from 1H-benzimidazole-2-ylmethanamine