Scientific Production Faculty

Quantification of As(III) by Swasv on Glassy Carbon Electrode Codeposit Copper with Presence of B-Ciclodextrin



Mendoza Huizar, Luis Humberto

2013

López-Vargas, E., Galán-Vidal, C.A., Rodríguez-Ávila, J.A., Álvarez-Romero, G.A. Mendoza-Huizar, L.H. ECS Trans.. 2013, 47(1), 131-136.


Abstract


Nowadays, the ability to detect arsenic in drinking water is a very important subject because of arsenic's toxicity. In this sense, it is necessary to have economical and portable detection methodologies in order to control water quality, mainly in remote communities without access to expensive equipment such as atomic absorption. Currently, electrochemical methods are a low cost alternative which can be used outside the laboratory; however, these techniques use toxic or precious metals as working electrodes. The main interference in the quantification of arsenic is the Cu(II) because an intermetallic compound is formed with arsenic. In this paper we explore the co-deposition of Cu on a glassy carbon electrode to quantify As(III) in H2SO4 as a supporting electrolyte. The methodology reported a detection limit of 5.2 ?g L-1, helpful to following the official guidelines. Zn2+, Fe2+, Pb2+, Hg2+ and Cl- are not significant interferences in quantification.



Research Product




Related articles

Electrochemical kinetic study about cobalt electrodeposition onto GCE and HOPG substrates from sulfa...

Influence of the Crystallinity of the Substrate on Kinetic Parameters of Zinc Electrodeposition Proc...

Quantum chemical study of the electrochemical reduction of the [Co(H2O)6]2+ and [Co(NH3)5(H2O)]2+ io...

Zinc Electrodeposition from Chloride Solutions onto Glassy Carbon Electrode

Nucleation and Growth Kinetics of Electrodeposited Sulfate-Doped Polypyrrole: Determination of the D...

Effect of support composition on the surface structures of nickel oxides and molybdenum and molybdenum oxides....

Cobalt Electrodeposition Process from Electrolytic Baths based on CoSO4 and (NH4)2SO4. Influence of ...

Morphological and magnetic properties of cobalt nanoclusters electrodeposited onto HOPG

Nucleation and Growth Kinetics of Electrodeposited Sulfate-Doped Polypyrrole: Determination of the D...

Study of the Humic Acid-Heavy Metal Interactions and Determination of their Stability Constants....